HydroquinoneCAS#123-31-9

  • High Purity & Crystalline Form – Appears as colorless or white crystals with a well-defined molecular structure, ensuring consistency for chemical applications.

  • Solubility Versatility – Easily soluble in hot water, ethanol, and ether, with slight solubility in benzene, enabling flexibility in formulation and processing.

  • Reactive Chemical Properties – Exhibits active chemical behavior, capable of undergoing oxidation, esterification, substitution, and other reactions.

  • Reliable Physical Characteristics – Possesses precise melting and boiling points (170–171°C and 285–287°C) and UV absorption at 288 nm, useful for quality control and analytical purposes.


Product Details

Product Description of Hydroquinone CAS#123-31-9

Hydroquinone, also known as 1,4-benzenediol, has the molecular formula C₆H₆O₂ and a molecular weight of 110.11. It appears as colorless or white crystals and is prone to color changes when exposed to light and air. Its aqueous solutions can turn brown upon oxidation, with the process accelerating in alkaline conditions.

Hydroquinone has a melting point of 170–171°C, a boiling point of 285–287°C, a relative density of 1.33215, and exhibits a maximum UV absorption at 288 nm in water. It is readily soluble in hot water, ethanol, and ether, and slightly soluble in benzene.

This compound possesses active chemical properties and is easily oxidized. It can also participate in various reactions, including esterification and substitution.

HydroquinoneCAS#123-31-9

Hydroquinone Chemical Properties

Melting point 

172-175 °C(lit.)

Boiling point 

285 °C(lit.)

density 

1.32

vapor density 

3.81 (vs air)

vapor pressure 

1 mm Hg ( 132 °C)

refractive index 

1.632

Fp 

165 °C

storage temp. 

Store below +30°C.

solubility 

H2O: 50 mg/mL, clear

pka

10.35(at 20℃)

form 

Needle-Like Crystals or Crystalline Powder

color 

White to off-white

Odor

odorless

Water Solubility 

70 g/L (20 ºC)

Sensitive 

Air & Light Sensitive

Merck 

144808

BRN 

605970

Henry's Law Constant

(x 10-9 atm?m3/mol): <2.07 at 20 °C (approximate - calculated from water solubility and vapor pressure)

Exposure limits

NIOSH REL: 15-min ceiling 2, IDLH 50; OSHA PEL: TWA 2; ACGIH TLV: TWA 2 (adopted).

Stability:

Stable. Combustible. Incompatible with strong oxidizing agents, strong bases, oxygen, ferric salts. Light and air-sensitive. Discolours in air.

InChIKey

QIGBRXMKCJKVMJ-UHFFFAOYSA-N

LogP

0.59 at 20℃

CAS DataBase Reference

123-31-9(CAS DataBase Reference)

NIST Chemistry Reference

Hydroquinone(123-31-9)

IARC

3 (Vol. 15, Sup 7, 71) 1999

EPA Substance Registry System

Hydroquinone (123-31-9)

Safety Information

Hazard Codes 

Xn,N

Risk Statements 

22-40-41-43-50-68-R68-R50-R43-R41-R40-R22

Safety Statements 

26-36/37/39-61-S61-S36/37/39-S26

RIDADR 

2662

WGK Germany 

3

RTECS 

MX3500000

Autoignition Temperature

930 °F

TSCA 

Yes

HazardClass 

9

PackingGroup 

III

HS Code 

29072210

Hazardous Substances Data

123-31-9(Hazardous Substances Data)

Toxicity

LD50 orally in rats: 320 mg/kg (Woodard)

IDLA

50 mg/m3

HydroquinoneCAS#123-31-9

Product Applications of Hydroquinone CAS#123-31-9

Hydroquinone is widely used in analytical chemistry and industrial applications. It can be applied in the colorimetric determination of phosphorus, magnesium, niobium, copper, silicon, and arsenic, as well as in the polarographic and volumetric determination of iridium.

It also functions as an effective reducing agent for heteropolyacids, copper, and gold, and is used in the testing of phosphate, tungstate, nitrate, nitrite, selenium, and tellurium. In addition, hydroquinone is commonly used as a developer, antioxidant, desulfurizer in the fertilizer industry, and as a urea synergist.

HydroquinoneCAS#123-31-9

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